HW 1 Ethers Key_page_1
CHEM 3332 Honors Homework for Epoxides, Ethers, and Thioethers 1. Draw a Lewis dot diagram for the following. A. Diethyl ether D.…
HW 1 Ethers Key_page_2
OH NaH Br F. OH NaH Br G. HI > MeO H. Ss PCC UO I. H CD m-CPBA H 77 multiple products fo HO
HW 1 Ethers Key_page_3
J. CO HOOH, NaOH ——— ° Se So fo) K. mCPBA —_> fe) re) fe) fe) L. Show the mechanism for this transformation, also. 1) Br2, HO nA~I—4 OOOO…
HW 1 Ethers Key_page_4
O. oO HBr (gas) SE ace > fe) HBr (aqueous) ———_> Br Ns, HO ou
HW 1 Ethers Key_page_5
3. Give reagents to perform the following transformations. A. What major byproduct would you expect? So O~t:0 H2SO,, reflux/distill OR 1)…
HW 1 Ethers Key_page_6
OO ~Cp 1) mCPBA 2) HCI, H20 J HO wo A —. jm ae ie) {e) NaH, heat K. OH OH HO AL 7 a y . io) fe) ‘Oo B F3: oO Et 4. Propose a mechanism for…
HW 1 Ethers Key_page_7
5. Give the transformations and reagents necessary to synthesize the compounds on the left from the compounds on the right. A. D : Cr” = om…
HW 1 Ethers Key_page_8
G. fe) OH nA” NN => AAW 6H 1) 1 equiv NaH; TsCl 2) NaH 6. Synthesize the following products using reasonable starting materials of 4…